Compound Interest: The Chemistry of Matches (2024)

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After fielding questions from students about what chemicals arein matches this week, it seemed like a good topic for a post looking at the question in more detail. When using matches on a day-to-day basis, you probably don’t think much of the chemical composition, or the reactions that are being set off; this graphic takes a look at some of the chemicals you can find in your average safety match, and the role they play.

Matches, as it turns out, have been around for a long time. Sulfur-based matches are mentioned as far back as the 1200s in texts of the time, and in the 1600s a process involving drawing sulfur matches through dried phosphorus-soaked paper was devised. However, the friction matches we’re used to have their origins in the 1800s; the first were developed by the English chemist, John Walker, in 1826. His matches involved a mixture of potassium chlorate, antimony (III) sulfide, gum andstarch, which ignited when struck on sandpaper. These matches were somewhat unreliable in whether or not they would successfully strike, however.

In 1830, Charles Sauria, a French chemist, invented the first phosphorus-based match, by replacing the antimony sulfide in Walker’s matches with white phosphorus. Whilst much easier to ignite, these matches, too, had issues. Although they were manufactured over a number of decades, the toxicity of white phosphorus slowly became apparent.The long term exposure to white phosphorus of those making the matches led to ‘phossy jaw’ – an affliction which caused toothaches, major swelling of the gums, disfigurement, and eventual brain damage. The only treatment was the removal of the jaw bone. As more about the toxicity of white phosphorus became known, it was eventually banned in 1906.

Prior to the banning, alternatives had already been sought for use in matches.In 1845, Anton Schrötter von Kristelli discovered that heating white phosphorus, or exposing it to sunlight, turned it into another form of the element: red phosphorus. This form of the element is non-toxic; technically, it is not an allotrope, but rather an intermediate form between white phosphorus and another allotrope, violet phosphorus. Safety matches were subsequently introduced using red phosphorus in the place of white phosphorus.

So how do the safety matches of today function? The red phosphorus is, in fact, no longer found in the head of the match – rather, it’s located on the striking surface on the side of the box, mixed with an abrasive substance such as powdered glass. The match head contains an oxidising agent, commonly potassium chlorate, and glue to bind it to further abrasive materials and other additive compounds. These can include antimony (III) sulfide and/or sulfur, added as fuel to helpthe match head burn.

When the match is struck, a small amount of the red phosphorus on the striking surface is converted into white phosphorus, which then ignites. The heat from this ignites the potassium chlorate,and the match head bursts into flame. During manufacture, the match stick itself is soaked in ammonium phosphate, which prevents ‘afterglow’ once the flame has gone out, and paraffin, which ensures that it burns easily.

Unlike safety matches, ‘strike anywhere’ matches don’t require the red phosphorus striking surface in order to ignite. This is because they contain phosphorus in the match head, in the form of phosphorus sesquisulfide. Other than this difference, however, they still function in much the same way.

You can see thechemical reaction that occurs when a match is struck happening in super-slow motion in this amazing video byAmerican cinematographer Alan Teitel(or with chemistry commentary from ACS Reactions here).If you want to find out more about the history of matches beyond this brief overview, check out the links below!

The graphic in this article is licensed under aCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. See the site’scontent usage guidelines.

References & Further Reading

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Compound Interest: The Chemistry of Matches (2024)

FAQs

Compound Interest: The Chemistry of Matches? ›

When the match is struck, a small amount of the red phosphorus on the striking surface is converted into white phosphorus, which then ignites. The heat from this ignites the potassium chlorate, and the match head bursts into flame.

What is the chemistry behind matches? ›

The head of "strike anywhere" matches contain an oxidizing agent such as potassium chlorate together with tetraphosphorus trisulfide, P₄S₃, glass and binder. The phosphorus sulfide is easily ignited, the potassium chlorate decomposes to give oxygen, which in turn causes the phosphorus sulfide to burn more vigorously.

What is the chemical reaction of the matchstick? ›

If the match is struck against the striking surface, the friction causes the match to heat up. A small amount of the red phosphorus on the friction surface is converted into white phosphorus. The heat ignites the phosphorus that has reached the match head of the match when rubbing.

What is the chemical formula for the match? ›

The match head contains a mixture of two chemicals, phosphorus sesquisulfide P4S3 and potassium chlorate(v), KClO3. When the match is struck, the heat of friction is sufficient to ignite the phosphorus sesquisulfide. The potassium chlorate(V) decomposes to provide the oxygen needed for the combustion.

What compound is used in safety matches? ›

The head of the safety match stick basically has a mixture of potassium chlorate along with phosphorus sulfide and glass binder that keeps them intact.

Why is red phosphorus illegal? ›

Because of the potential use of red phosphorus for illicit drug manufacture (methamphetamine), its sale is monitored by the US Drug Enforcement Administration, which limits its availability in the United States.

Why do matches smell so good? ›

This oxygen combines with antimony trisulfide to produce a long-lasting flame so you have enough time to light a candle. The whole thing is coated with paraffin wax, which helps the flame travel down the match. Just don't burn the house down. As antimony oxidizes, sulfur oxides form, creating that burnt-match scent.

Are matches toxic to humans? ›

Generally, matches are not toxic, and most cases will not require medical attention. The most common side effect is an upset stomach. However, there are a few special cases that need to be considered: How many matches did your child eat, and were the matches recently lit?

Is a match burning a chemical change? ›

Since combustion is a chemical reaction involving reaction with oxygen forming new products, burning of matchstick is a chemical change.

What are some interesting facts about matches? ›

Red phosphorus is a key component of safety matches, a chemical that plays a crucial role in the ignition process. The striking surface on the matchbox or case contains a small amount of red phosphorus. When you strike the match against this surface, the friction causes a chemical reaction that ignites the match head.

What acid is used in matches? ›

Modern safety matches usually have antimony sulfide, oxidizing agents such as potassium chlorate, and sulfur or charcoal in the heads, and red phosphorus in the striking surface. Nonsafety matches usually have phosphorus sesquisulfide in the heads.

What is the molecular structure of matches? ›

In this work, two molecular structures are considered to be a "match", if the smaller structure is an exact substructure (atom and bond types) of the larger structure being compared.

Why is red phosphorus used in matches? ›

The friction between the match and the striking surface causes the match to heat up. On the friction surface, a small amount of red phosphorus is transformed into white phosphorus. Red phosphorus has a low ignition temperature. Thus, it is used in the manufacturing of safety matches.

Is potassium used in matches? ›

Potassium chlorate (KClO3) is a highly reactive oxidizing agent commonly used in matchstick heads, explosives, flares, pyrotechnics, textile printing, bleaching and disinfectants [1].

What element is used in matches and fertilizers? ›

Red phosphorus is in the material stuck on the side of matchboxes, used to strike safety matches against to light them. By far the largest use of phosphorus compounds is for fertilisers.

Which compound of P is used to manufacture strike anywhere matches? ›

(h) A chemical compound that makes up the striking heads of match sticks is phosphorus sulphide.

What is the chemical energy in a match? ›

Energy stored in an unburned match is basically in the form of chemical energy which comes from the inflammable material the matches are made with (Phosphorus & Sulphur mainly). Chemical energy is converted into heat, light & sound energy at the time of burning.

How does a match have chemical energy? ›

The head of the matchstick consists of combustible substances which possess stored energy, i.e., chemical energy. When a matchstick is rubbed against a suitable surface the combustible substances start to burn with the evolution of heat and light energy.

What source of energy is matches? ›

Lighting a fire with a match uses chemical energy, thermal energy and light energy. A match has stored energy in the chemicals coating it in the form of chemical energy. When a match is lit the chemical energy in it is converted to heat and light energy in the flame. This is an example of an energy conversion.

Do matches have harmful chemicals? ›

The chemicals in the match head can cause damage to the kidneys and liver (this is rare). If the matches were lit not long before they were swallowed, there is danger that they could cause an internal burn. Like most small objects, they can also be a choking hazard. In these cases, seek immediate help and call 911.

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